The Hydrogen‐Storage Challenge: Nanoparticles for Metal‐Catalyzed Ammonia Borane Dehydrogenation

Dihydrogen is one of the sustainable energy vectors envisioned for the future. However, the rapidly reversible and secure storage of large quantities of hydrogen is still a technological and scientific challenge. In this context, this review proposes a recent state‐of‐the‐art on H2 production capacities from the dehydrogenation reaction of ammonia borane (and selected related amine‐boranes) as a safer solid source of H2 by hydrolysis (or solvolysis), catalyzed by nanoparticle‐based systems. The review groups the results according to the transition metals constituting the catalyst with a mention to their current cost and availability. This includes the noble metals Rh, Pd, Pt, Ru, Ag, as well as cheaper Co, Ni, Cu, and Fe. For each element, the monometallic and polymetallic structures are presented and the performances are described in terms of turnover frequency and recyclability. The structure–property links are highlighted whenever possible. It appears from all these works that the mastery of the preparation of catalysts remains a crucial point both in terms of process, and control and understanding of the electronic structures of the elaborated nanomaterials. A particular effort of the scientific community remains to be made in this multidisciplinary field with major societal stakes. Dihydrogen conventional physical storage under high pressure or low temperature, under gas or liquid forms, remains delicate from technological requirement and societal acceptability. This review provides a recent state‐of‐the‐art on H2 production capacities from the dehydrogenation reaction of ammonia borane as a safer solid source of H2, by hydrolysis, according to the different nanocatalysts built on noble and non‐noble metals.