Controlled Access to C 1 ‐Symmetrical Cyclotriveratrylenes (CTVs) by Using a Sequential Barluenga Boronic Coupling (BBC) Approach

Controlled Access to C 1 ‐Symmetrical Cyclotriveratrylenes (CTVs) by Using a Sequential Barluenga Boronic Coupling (BBC) Approach

We describe here a controlled approach to C 1 ‐symmetrical cyclotriveratrylenes (CTVs). In this approach dimers are synthesized through Barluenga boronic coupling (BBC) and after borylation, the last aromatic ring is introduced by a second BBC. After functional transformations of the trimers, the CT...

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Veröffentlicht in:Advanced synthesis & catalysis 2021-08, Vol.363 (15), p.3756-3761
Hauptverfasser: Vigier, Clément, Fossé, Pierre, Fabis, Frédéric, Cailly, Thomas, Dubost, Emmanuelle
Format: Artikel
Sprache:eng
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Chemical Sciences
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Zusammenfassung:We describe here a controlled approach to C 1 ‐symmetrical cyclotriveratrylenes (CTVs). In this approach dimers are synthesized through Barluenga boronic coupling (BBC) and after borylation, the last aromatic ring is introduced by a second BBC. After functional transformations of the trimers, the CTVs are formed using intramolecular SEAr. magnified image
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.202100547