In situ determination of sulfur speciation and partitioning in aqueous fluid-silicate melt systems
Current knowledge of sulfur behaviour in magmas is based exclusively on ex situ analyses. Here we report the first in situ measurement of sulfur speciation and partitioning between coexisting aqueous fluids and silicate melts. These data were acquired using Raman spectroscopy in a diamond anvil cell...
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Veröffentlicht in: | Geochemical perspectives letters 2020, Vol.14, p.31-35 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Current knowledge of sulfur behaviour in magmas is based exclusively on ex situ analyses. Here we report the first in situ measurement of sulfur speciation and partitioning between coexisting aqueous fluids and silicate melts. These data were acquired using Raman spectroscopy in a diamond anvil cell at 700 °C, 0.3–1.5 GPa, and oxygen fugacity in the vicinity of the sulfide-sulfate transition, conditions relevant to subduction zone magmatism. Results show that sulfate and sulfide are dominant in the studied systems, together with the and radical ions that are absent in quenched fluid and silicate glass products. The derived fluid/melt partition coefficients for sulfide and sulfate are consistent with those from available ex situ data for shallow crust conditions ( |
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ISSN: | 2410-3403 2410-339X 2410-3403 |
DOI: | 10.7185/geochemlet.2020 |