Directed synthesis of a halogen-bonded open porphyrin network

Directed synthesis of a halogen-bonded open porphyrin network

A strategy for the elaboration of a halogen-bonded porphyrin network is reported. The progressive introduction of geometric constraints via the modulation of building blocks and self-assembly via strong and directional halogen bonding led successfully to the construction of an open porphyrin network...

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Veröffentlicht in:CrystEngComm 2014-01, Vol.16 (45), p.10380-10384
Hauptverfasser: Syssa-Magalé, Jean-Laurent, Boubekeur, Kamal, Leroy, Jacques, Chamoreau, Lise-Marie, Fave, Claire, Schöllhorn, Bernd
Format: Artikel
Sprache:eng
Schlagworte:
Bonding
Channels
Chemical Sciences
Halogens
Modulation
Networks
Porphyrins
Self assembly
Strategy
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Zusammenfassung:A strategy for the elaboration of a halogen-bonded porphyrin network is reported. The progressive introduction of geometric constraints via the modulation of building blocks and self-assembly via strong and directional halogen bonding led successfully to the construction of an open porphyrin network with nano-sized tubular channels.
ISSN:1466-8033
1466-8033
DOI:10.1039/C4CE01704H