Alkenyl boost for Catellani

The Catellani reaction is a multi-component cascade sequence, catalysed by palladium and norbornene, which typically uses aromatic starting materials. Now, through the use of a modified norbornene co-catalyst, the scope of this reaction has been extended to alkenyl reagents, enabling the preparation...

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Veröffentlicht in:	Nature chemistry 2019-12, Vol.11 (12), p.1082-1084
Hauptverfasser:	Maestri, Giovanni, Derat, Etienne
Format:	Artikel
Sprache:	eng
Schlagworte:	639/638/403/933 639/638/549/933 639/638/77/888 Alkenes Analytical Chemistry Biochemistry Catalysts Chemical Sciences Chemistry Chemistry and Materials Science Chemistry/Food Science Inorganic Chemistry News & Views news-and-views Organic Chemistry Palladium Physical Chemistry Reagents
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Beschreibung
Zusammenfassung:	The Catellani reaction is a multi-component cascade sequence, catalysed by palladium and norbornene, which typically uses aromatic starting materials. Now, through the use of a modified norbornene co-catalyst, the scope of this reaction has been extended to alkenyl reagents, enabling the preparation of all-carbon tetrasubstituted olefins.
ISSN:	1755-4330 1755-4349
DOI:	10.1038/s41557-019-0361-3