Optimization of the dwell-time for the quantitative analysis by gas chromatography-mass spectrometry
In this paper, the signal path in mass spectrometer used as a detector for gas chromatography in the selected ion monitoring mode is analyzed. The process involved an accumulation step that can be considered as a digital filter. Thus the Nyquist criterion alone is to be taken into account for the ac...
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| Veröffentlicht in: | Journal of Chromatography A 1997, Vol.765 (2), p.241-245 |
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| container_end_page | 245 |
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| container_title | Journal of Chromatography A |
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| creator | Eveleigh, Luc J. Ducauze, Christian J. |
| description | In this paper, the signal path in mass spectrometer used as a detector for gas chromatography in the selected ion monitoring mode is analyzed. The process involved an accumulation step that can be considered as a digital filter. Thus the Nyquist criterion alone is to be taken into account for the acquisition, by contrast to what appends with other detectors which require a higher number of acquired points to minimize the error during peak integration. This theoretical assumption was tested and accepted for three different levels of signal-to-noise ratio. |
| doi_str_mv | 10.1016/S0021-9673(96)00939-9 |
| format | Article |
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This theoretical assumption was tested and accepted for three different levels of signal-to-noise ratio.</description><subject>Alkanes</subject><subject>Analytical chemistry</subject><subject>Chemical Physics</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Detection</subject><subject>Dwell time</subject><subject>Exact sciences and technology</subject><subject>Gas chromatographic methods</subject><subject>Mass spectrometry</subject><subject>Physics</subject><subject>Signal-to-noise ratio</subject><issn>0021-9673</issn><issn>1873-3778</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhoMoWKs_QcjBgx5WM0mz2ZykiF9Q8KCewzSbbSPb3TWJlfXXu22lVy8ZeHneCfMQcg7sGhjkN6-Mcch0rsSlzq8Y00Jn-oCMoFAiE0oVh2S0R47JSYwfjIFiio9I-dIlv_I_mHzb0Laiaelo-e3qOhtyR6s2bKPPL2ySTwO2dhQbrPvoI533dIGR2mVoV5jaRcBu2WcrjJHGztk0xC6F_pQcVVhHd_Y3x-T94f7t7imbvTw-301nmRWMp0wxtDgXjkvI5RwkSDHnpWMTDhwKXuRSTqoCdC5tWVquCq24FMCFqlDoCYgxudrtXWJtuuBXGHrTojdP05nZZIznutByst6wcsfa0MYYXLUvADMbrWar1WycDY_ZajV66F3seh1Gi3UVsLE-7ss85wBKDtjtDnPDvWvvgonWu8a60odBjClb_89Hv-6ji_M</recordid><startdate>1997</startdate><enddate>1997</enddate><creator>Eveleigh, Luc J.</creator><creator>Ducauze, Christian J.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope></search><sort><creationdate>1997</creationdate><title>Optimization of the dwell-time for the quantitative analysis by gas chromatography-mass spectrometry</title><author>Eveleigh, Luc J. ; Ducauze, Christian J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c302t-70acab3e25165b15153b2de0421218286554f81965cddc278972531237fa39413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>Alkanes</topic><topic>Analytical chemistry</topic><topic>Chemical Physics</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>Detection</topic><topic>Dwell time</topic><topic>Exact sciences and technology</topic><topic>Gas chromatographic methods</topic><topic>Mass spectrometry</topic><topic>Physics</topic><topic>Signal-to-noise ratio</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Eveleigh, Luc J.</creatorcontrib><creatorcontrib>Ducauze, Christian J.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of Chromatography A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Eveleigh, Luc J.</au><au>Ducauze, Christian J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Optimization of the dwell-time for the quantitative analysis by gas chromatography-mass spectrometry</atitle><jtitle>Journal of Chromatography A</jtitle><date>1997</date><risdate>1997</risdate><volume>765</volume><issue>2</issue><spage>241</spage><epage>245</epage><pages>241-245</pages><issn>0021-9673</issn><eissn>1873-3778</eissn><coden>JOCRAM</coden><abstract>In this paper, the signal path in mass spectrometer used as a detector for gas chromatography in the selected ion monitoring mode is analyzed. 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| ispartof | Journal of Chromatography A, 1997, Vol.765 (2), p.241-245 |
| issn | 0021-9673 1873-3778 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Alkanes Analytical chemistry Chemical Physics Chemistry Chromatographic methods and physical methods associated with chromatography Detection Dwell time Exact sciences and technology Gas chromatographic methods Mass spectrometry Physics Signal-to-noise ratio |
| title | Optimization of the dwell-time for the quantitative analysis by gas chromatography-mass spectrometry |
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