Oxidation of Unactivated Primary Aliphatic Amines Catalyzed by an Electrogenerated 3,4-Azaquinone Species: A Small-Molecule Mimic of Amine Oxidases

High catalytic performance of the electrogenerated amine oxidase mimic 3,4‐iminoquinone 1ox is observed under metal‐free conditions in the chemoselective oxidation reaction of unactivated primary aliphatic amines.

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition 2003-03, Vol.42 (9), p.1026-1029
Hauptverfasser:	Largeron, Martine, Neudorffer, Anne, Fleury, Maurice-Bernard
Format:	Artikel
Sprache:	eng
Schlagworte:	Amine Oxidase (Copper-Containing) - chemistry Amine Oxidase (Copper-Containing) - metabolism amines Amines - chemistry Biomimetics Catalysis Chemical Sciences chemoselectivity Electrochemistry enzyme models Molecular Structure Organic chemistry oxidation Oxidation-Reduction Quinones - chemistry
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Beschreibung
Zusammenfassung:	High catalytic performance of the electrogenerated amine oxidase mimic 3,4‐iminoquinone 1ox is observed under metal‐free conditions in the chemoselective oxidation reaction of unactivated primary aliphatic amines.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200390263