Surface confined self-assembly of polyampholytes generated from charge-shifting polymers

Surface confined self-assembly of polyampholytes generated from charge-shifting polymers

Polyampholyte-based films can be efficiently self-assembled onto a surface in a one-pot manner. By using a gradient of protons, morphogens, generated at an electrode surface, a charge-shifting polyelectrolyte present in solution can be transformed into a polyampholyte, leading to the continuous buil...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-09, Vol.51 (74), p.14092-14095
Hauptverfasser: Garnier, T, Dochter, A, Chau, N T T, Schaaf, P, Jierry, L, Boulmedais, F
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Citraconic Anhydrides - chemistry
Complexation
Construction
Electrodes
Electrolytes - chemistry
Molecular Structure
Polyamines - chemistry
Polyampholytes
Polyelectrolytes
Polymers
Polymers - chemistry
Self assembly
Static Electricity
Surface Properties
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Beschreibung
Zusammenfassung:Polyampholyte-based films can be efficiently self-assembled onto a surface in a one-pot manner. By using a gradient of protons, morphogens, generated at an electrode surface, a charge-shifting polyelectrolyte present in solution can be transformed into a polyampholyte, leading to the continuous buildup of a film based on polyelectrolyte complexation.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc04477d