Hydride transfer reactions in dimolybdenum compounds: a simple route to the novel μ-η1∶η1-tetrahydroboride complex [Mo2Cp2(μ-SMe)3(μ-BH4)]

Hydride transfer reactions in dimolybdenum compounds: a simple route to the novel μ-η1∶η1-tetrahydroboride complex [Mo2Cp2(μ-SMe)3(μ-BH4)]

The reaction of NaBH4 with the bis-nitrile compound [Mo2Cp2(μ-SMe)3(MeCN)2](BF4) 1 unexpectedly gives rise to the rare, stable μ-(η1-H)(η1-H) tetrahydroborato complex [Mo2Cp2(μ-SMe)3(μ-BH4)] 2, in addition to the expected azavinylidene product [Mo2Cp2(μ-SMe)3(μ-η1-NCHMe)] 3.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2000 (21), p.2137-2138
Hauptverfasser: Schollhammer, Philippe, Cabon, Nolwenn, Pétillon, François Y., Talarmin, Jean, Muir, Kenneth W.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
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Zusammenfassung:The reaction of NaBH4 with the bis-nitrile compound [Mo2Cp2(μ-SMe)3(MeCN)2](BF4) 1 unexpectedly gives rise to the rare, stable μ-(η1-H)(η1-H) tetrahydroborato complex [Mo2Cp2(μ-SMe)3(μ-BH4)] 2, in addition to the expected azavinylidene product [Mo2Cp2(μ-SMe)3(μ-η1-NCHMe)] 3.
ISSN:1359-7345
1364-548X
DOI:10.1039/b006457m