Influence of the Microstructural Texture of Cast Superalloys on their High-Temperature Oxidation Behaviour

The high-temperature oxidation behaviours of Ni base and Co base cast superalloys were studied to determine the effect of different grain sizes and different surface dendritic orientations. These microstructural characteristics were obtained by varying solidification rate and cutting orientation with regard to the external surface. Thermogravimetry tests were run at 1000 and 1100°C and parabolic oxidation constants were considered. It appears that oxidation is faster for fine microstructures than for coarser ones for Ni or Co alloys including tungsten in their chemical composition, while it is the contrary when W is not present. When the sample surface is mainly parallel to the dendritic network, the oxidation rate is greater than for a surface perpendicular to dendrites, for the studied Ni alloy. The same phenomenon is observed for the studied Co base alloy at 1100°C but the order is inverted at 1000°C. These different behaviours can be explained by the grain boundary densities and orientations obtained on surface, since they can influence the diffusion of species involved in the oxidation phenomena. It is also possible that the characteristics of the chromia scale, such as grain size and general quality, depend on the microstructural texture of the alloy.