Terarylenes as Photoactivatable Hydride Donors

Terarylene frameworks containing benzothiazole as a photoprecursor of hydride donors are presented. We here report on two new scaffolds along with their photoreactivity in solution. Through use of selected external oxidants, the photogeneration of hydride donors is monitored using UV–visible, NMR, a...

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Veröffentlicht in:	Journal of organic chemistry 2018-11, Vol.83 (22), p.13700-13706
Hauptverfasser:	Martin, Colin J, Minamide, Miho, Dela Cruz Calupitan, Jan Patrick, Asato, Ryosuke, Kuno, Jumpei, Nakashima, Takuya, Rapenne, Gwénaël, Kawai, Tsuyoshi
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Sprache:	eng
Schlagworte:	Chemical Sciences Organic chemistry
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container_end_page	13706
container_issue	22
container_start_page	13700
container_title	Journal of organic chemistry
container_volume	83
creator	Martin, Colin J Minamide, Miho Dela Cruz Calupitan, Jan Patrick Asato, Ryosuke Kuno, Jumpei Nakashima, Takuya Rapenne, Gwénaël Kawai, Tsuyoshi
description	Terarylene frameworks containing benzothiazole as a photoprecursor of hydride donors are presented. We here report on two new scaffolds along with their photoreactivity in solution. Through use of selected external oxidants, the photogeneration of hydride donors is monitored using UV–visible, NMR, and TEM methods. As a proof-of-concept, photogeneration of hydride in the presence of Ag+ gave rise to the formation of Ag nanoparticles.
doi_str_mv	10.1021/acs.joc.8b01877
format	Article
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subjects	Chemical Sciences Organic chemistry
title	Terarylenes as Photoactivatable Hydride Donors
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