Terarylenes as Photoactivatable Hydride Donors

Terarylenes as Photoactivatable Hydride Donors

Terarylene frameworks containing benzothiazole as a photoprecursor of hydride donors are presented. We here report on two new scaffolds along with their photoreactivity in solution. Through use of selected external oxidants, the photogeneration of hydride donors is monitored using UV–visible, NMR, a...

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Veröffentlicht in:Journal of organic chemistry 2018-11, Vol.83 (22), p.13700-13706
Hauptverfasser: Martin, Colin J, Minamide, Miho, Dela Cruz Calupitan, Jan Patrick, Asato, Ryosuke, Kuno, Jumpei, Nakashima, Takuya, Rapenne, Gwénaël, Kawai, Tsuyoshi
Format: Artikel
Sprache:eng
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Chemical Sciences
Organic chemistry
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Zusammenfassung:Terarylene frameworks containing benzothiazole as a photoprecursor of hydride donors are presented. We here report on two new scaffolds along with their photoreactivity in solution. Through use of selected external oxidants, the photogeneration of hydride donors is monitored using UV–visible, NMR, and TEM methods. As a proof-of-concept, photogeneration of hydride in the presence of Ag+ gave rise to the formation of Ag nanoparticles.
ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.8b01877