An efficient and simple one-pot synthesis of 2-perfluoroalkylated benzo[1,3]dioxole derivatives via double–Michael reaction of fluorinated alkynes
[Display omitted] •Efficient regioselective synthesis of 2-fluoroalkylated-benzo[d][1,3]dioxoles. Synthesis of fluoroalkylated benzoxazolines and benzothiazoline. Double-Michael reaction. An efficient, mild and very easy method for the synthesis of 2-fluoroalkylated 1,3-benzodioxole derivatives was...
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| Veröffentlicht in: | Journal of fluorine chemistry 2018-08, Vol.212, p.45-50 |
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| container_title | Journal of fluorine chemistry |
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| creator | Ella Ndong, Guy Judicaël Jismy, Badr Inack Ngi, Samuel Abarbri, Mohamed |
| description | [Display omitted]
•Efficient regioselective synthesis of 2-fluoroalkylated-benzo[d][1,3]dioxoles. Synthesis of fluoroalkylated benzoxazolines and benzothiazoline. Double-Michael reaction.
An efficient, mild and very easy method for the synthesis of 2-fluoroalkylated 1,3-benzodioxole derivatives was developed through a double Michael-addition reaction on ethyl 4,4,4-trifluorobut-2-ynoate with corresponding catechols. The procedure does not require the use of expensive supplementary additives for the preparation of 2-fluoroalkylated benzo ketals. |
| doi_str_mv | 10.1016/j.jfluchem.2018.05.005 |
| format | Article |
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•Efficient regioselective synthesis of 2-fluoroalkylated-benzo[d][1,3]dioxoles. Synthesis of fluoroalkylated benzoxazolines and benzothiazoline. Double-Michael reaction.
An efficient, mild and very easy method for the synthesis of 2-fluoroalkylated 1,3-benzodioxole derivatives was developed through a double Michael-addition reaction on ethyl 4,4,4-trifluorobut-2-ynoate with corresponding catechols. The procedure does not require the use of expensive supplementary additives for the preparation of 2-fluoroalkylated benzo ketals.</description><identifier>ISSN: 0022-1139</identifier><identifier>EISSN: 1873-3328</identifier><identifier>DOI: 10.1016/j.jfluchem.2018.05.005</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Additives ; Alkynes ; Benzothiazoline ; Catechols ; Chemical Sciences ; Chemical synthesis ; Derivatives ; Double Michael-addition ; Fluorides ; Fluorination ; Fluorine ; Fluoroalkylated 1,3-benzodioxoles ; Fluoroalkylated alkynes ; Fluoroalkylated benzoxazolines ; Hydrocarbons ; Michael reaction ; Organic chemistry</subject><ispartof>Journal of fluorine chemistry, 2018-08, Vol.212, p.45-50</ispartof><rights>2018 Elsevier B.V.</rights><rights>Copyright Elsevier BV Aug 2018</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c321t-3135ed4db0f64d8223a41e525a5e65d22c103682e65311d67c3746ddec49bb5e3</cites><orcidid>0000-0001-9654-7497 ; 0000-0002-6742-1075</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jfluchem.2018.05.005$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02055652$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Ella Ndong, Guy Judicaël</creatorcontrib><creatorcontrib>Jismy, Badr</creatorcontrib><creatorcontrib>Inack Ngi, Samuel</creatorcontrib><creatorcontrib>Abarbri, Mohamed</creatorcontrib><title>An efficient and simple one-pot synthesis of 2-perfluoroalkylated benzo[1,3]dioxole derivatives via double–Michael reaction of fluorinated alkynes</title><title>Journal of fluorine chemistry</title><description>[Display omitted]
•Efficient regioselective synthesis of 2-fluoroalkylated-benzo[d][1,3]dioxoles. Synthesis of fluoroalkylated benzoxazolines and benzothiazoline. Double-Michael reaction.
An efficient, mild and very easy method for the synthesis of 2-fluoroalkylated 1,3-benzodioxole derivatives was developed through a double Michael-addition reaction on ethyl 4,4,4-trifluorobut-2-ynoate with corresponding catechols. The procedure does not require the use of expensive supplementary additives for the preparation of 2-fluoroalkylated benzo ketals.</description><subject>Additives</subject><subject>Alkynes</subject><subject>Benzothiazoline</subject><subject>Catechols</subject><subject>Chemical Sciences</subject><subject>Chemical synthesis</subject><subject>Derivatives</subject><subject>Double Michael-addition</subject><subject>Fluorides</subject><subject>Fluorination</subject><subject>Fluorine</subject><subject>Fluoroalkylated 1,3-benzodioxoles</subject><subject>Fluoroalkylated alkynes</subject><subject>Fluoroalkylated benzoxazolines</subject><subject>Hydrocarbons</subject><subject>Michael reaction</subject><subject>Organic chemistry</subject><issn>0022-1139</issn><issn>1873-3328</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkdGK1DAUhou44Lj6ChLwSrD1JGnS9s5hUVcY8Wb3SiSkySmT2klq0imOV76DPuE-ie2OeutVOOH_v5PwZdkzCgUFKl_1Rd8NR7PHQ8GA1gWIAkA8yDa0rnjOOasfZhsAxnJKefMoe5xSDwAVVPUm-7X1BLvOGYd-ItpbktxhHJAEj_kYJpJOftpjcomEjrB8xLgsCzHo4ctp0BNa0qL_Hj7Rl_yzdeFbWLoWo5v15GZMZHaa2HBsB7z78fODM3uNA4mozeSCX5n3OOfvUSvUY3qSXXR6SPj0z3mZ3b59c3N1ne8-vnt_td3lhjM65Zxygba0LXSytDVjXJcUBRNaoBSWMUOBy5otA6fUysrwqpTWoimbthXIL7MXZ-5eD2qM7qDjSQXt1PV2p9Y7YCCEFGymS_b5OTvG8PWIaVJ9OEa_PE8xaJqmKqGUS0qeUyaGlCJ2_7AU1GpL9eqvLbXaUiDUYmspvj4Xcfnv7DCqtCoxaF1EMykb3P8QvwEk6aQY</recordid><startdate>201808</startdate><enddate>201808</enddate><creator>Ella Ndong, Guy Judicaël</creator><creator>Jismy, Badr</creator><creator>Inack Ngi, Samuel</creator><creator>Abarbri, Mohamed</creator><general>Elsevier B.V</general><general>Elsevier BV</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QP</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>7U7</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-9654-7497</orcidid><orcidid>https://orcid.org/0000-0002-6742-1075</orcidid></search><sort><creationdate>201808</creationdate><title>An efficient and simple one-pot synthesis of 2-perfluoroalkylated benzo[1,3]dioxole derivatives via double–Michael reaction of fluorinated alkynes</title><author>Ella Ndong, Guy Judicaël ; Jismy, Badr ; Inack Ngi, Samuel ; Abarbri, Mohamed</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c321t-3135ed4db0f64d8223a41e525a5e65d22c103682e65311d67c3746ddec49bb5e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Additives</topic><topic>Alkynes</topic><topic>Benzothiazoline</topic><topic>Catechols</topic><topic>Chemical Sciences</topic><topic>Chemical synthesis</topic><topic>Derivatives</topic><topic>Double Michael-addition</topic><topic>Fluorides</topic><topic>Fluorination</topic><topic>Fluorine</topic><topic>Fluoroalkylated 1,3-benzodioxoles</topic><topic>Fluoroalkylated alkynes</topic><topic>Fluoroalkylated benzoxazolines</topic><topic>Hydrocarbons</topic><topic>Michael reaction</topic><topic>Organic chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ella Ndong, Guy Judicaël</creatorcontrib><creatorcontrib>Jismy, Badr</creatorcontrib><creatorcontrib>Inack Ngi, Samuel</creatorcontrib><creatorcontrib>Abarbri, Mohamed</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Calcium & Calcified Tissue Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Toxicology Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of fluorine chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ella Ndong, Guy Judicaël</au><au>Jismy, Badr</au><au>Inack Ngi, Samuel</au><au>Abarbri, Mohamed</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An efficient and simple one-pot synthesis of 2-perfluoroalkylated benzo[1,3]dioxole derivatives via double–Michael reaction of fluorinated alkynes</atitle><jtitle>Journal of fluorine chemistry</jtitle><date>2018-08</date><risdate>2018</risdate><volume>212</volume><spage>45</spage><epage>50</epage><pages>45-50</pages><issn>0022-1139</issn><eissn>1873-3328</eissn><abstract>[Display omitted]
•Efficient regioselective synthesis of 2-fluoroalkylated-benzo[d][1,3]dioxoles. Synthesis of fluoroalkylated benzoxazolines and benzothiazoline. Double-Michael reaction.
An efficient, mild and very easy method for the synthesis of 2-fluoroalkylated 1,3-benzodioxole derivatives was developed through a double Michael-addition reaction on ethyl 4,4,4-trifluorobut-2-ynoate with corresponding catechols. The procedure does not require the use of expensive supplementary additives for the preparation of 2-fluoroalkylated benzo ketals.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jfluchem.2018.05.005</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-9654-7497</orcidid><orcidid>https://orcid.org/0000-0002-6742-1075</orcidid></addata></record> |
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| language | eng |
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| subjects | Additives Alkynes Benzothiazoline Catechols Chemical Sciences Chemical synthesis Derivatives Double Michael-addition Fluorides Fluorination Fluorine Fluoroalkylated 1,3-benzodioxoles Fluoroalkylated alkynes Fluoroalkylated benzoxazolines Hydrocarbons Michael reaction Organic chemistry |
| title | An efficient and simple one-pot synthesis of 2-perfluoroalkylated benzo[1,3]dioxole derivatives via double–Michael reaction of fluorinated alkynes |
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