2D 7 Li Ultrafast CT-COSY: a new tool for the rapid measurement of tiny homonuclear lithium scalar couplings

2D 7 Li Ultrafast CT-COSY: a new tool for the rapid measurement of tiny homonuclear lithium scalar couplings

The measurement of small homonuclear 2 J 7Li–7Li scalar couplings relying on constant time (CT) COSY NMR suffers from strong time limitations. We describe the first Ultrafast CT COSY experiment on lithium 7, which provides a considerable acceleration in the study of the aggregation state and dynamic...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (1), p.220-223
Hauptverfasser: Hamdoun, G., Gouilleux, B., Sebban, M., Barozzino-Consiglio, G., Harrison-Marchand, A., Giraudeau, P., Maddaluno, J., Oulyadi, H.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Organic chemistry
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Zusammenfassung:The measurement of small homonuclear 2 J 7Li–7Li scalar couplings relying on constant time (CT) COSY NMR suffers from strong time limitations. We describe the first Ultrafast CT COSY experiment on lithium 7, which provides a considerable acceleration in the study of the aggregation state and dynamics of n -BuLi/MeLi complexes.
ISSN:1359-7345
1364-548X
DOI:10.1039/C6CC08744B