Frontispiece: A Hexakis Terpyridine-Fullerene Ligand in Six-Fold Ruthenium, Iridium, and Iron Complexes: Synthesis and Electrochemical Properties

Octahedral Fullerenes C60 is a unique platform to access highly symmetrical fullerene derivatives through the Bingel–Hirsch reaction. In their Communication on page 11522 ff., S. Bräse et al. report the straightforward introduction of six‐fold terpyridine ligands in octahedral position around C60. More importantly, it was demonstrated that this ligand is suitable to prepare the corresponding ruthenium, iridium and iron complexes that were fully and unambiguously characterized. This work undoubtedly opens the way to the preparation of 3D nanostructures.