Catalytic "triangles": binding of iron in task-specific ionic liquids

Catalytic "triangles": binding of iron in task-specific ionic liquids

A new class of task-specific ionic liquids (ILs) which contain septuply positively charged {Fe(3)(III)O(RCOO)(6)L(3)}(7+) triangles has been synthesized and structurally characterized. Such metal-containing ILs can be repeatedly used as alternative catalysts in the synthesis of 2-pyrrolo-3'-ylo...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (19), p.1915-1917
Hauptverfasser: Prodius, Denis, Macaev, Fliur, Stingaci, Eugenia, Pogrebnoi, Vsevolod, Mereacre, Valeriu, Novitchi, Ghenadie, Kostakis, George E, Anson, Christopher E, Powell, Annie K
Format: Artikel
Sprache:eng
Schlagworte:
Binding
Catalysis
Catalysts
Charging
Chemical Sciences
Condensing
Ionic liquids
Iron
Triangles
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Beschreibung
Zusammenfassung:A new class of task-specific ionic liquids (ILs) which contain septuply positively charged {Fe(3)(III)O(RCOO)(6)L(3)}(7+) triangles has been synthesized and structurally characterized. Such metal-containing ILs can be repeatedly used as alternative catalysts in the synthesis of 2-pyrrolo-3'-yloxindole or the condensation of indoles with various aldehydes.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc36741f