A family of 'windmill'-like {Cu 6 Ln 12 } complexes exhibiting single-molecule magnetism behavior and large magnetic entropy changes

A family of 'windmill'-like {Cu 6 Ln 12 } complexes exhibiting single-molecule magnetism behavior and large magnetic entropy changes

A family of nanosized {Cu Ln } clusters with a 'windmill'-like topology was prepared from the employment of 2,6-diacetylpyridine dioxime, in conjunction with bridging N , in 3d/4f-metal chemistry; the octadecanuclear compounds exhibit single-molecule magnetism behavior and large magnetic e...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (30), p.4266-4269
Hauptverfasser: Alexandropoulos, Dimitris I, Poole, Katye M, Cunha-Silva, Luis, Ahmad Sheikh, Javeed, Wernsdorfer, Wolfgang, Christou, George, Stamatatos, Theocharis C
Format: Artikel
Sprache:eng
Schlagworte:
Bridging
Chemical Sciences
Clusters
Employment
Entropy
Magnetism
Nanostructure
Topology
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Zusammenfassung:A family of nanosized {Cu Ln } clusters with a 'windmill'-like topology was prepared from the employment of 2,6-diacetylpyridine dioxime, in conjunction with bridging N , in 3d/4f-metal chemistry; the octadecanuclear compounds exhibit single-molecule magnetism behavior and large magnetic entropy changes, depending on the 4f-metal ion present.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc01382e