Synthesis and structural analysis of new macrocycles exhibiting 3,9-dimethyl-3,9-diaryl-2,4,8,10-tetraoxaspiro[5.5]undecane units

Synthesis and structural analysis of new macrocycles exhibiting 3,9-dimethyl-3,9-diaryl-2,4,8,10-tetraoxaspiro[5.5]undecane units

The template synthesis of a new series of macrocycles (from monomers to tetramers) with 2,4.8,10-tetraoxaspiro[5.5]undecane units is reported. The structural analysis of the compounds is carried out using the data of high field NMR investigations, mass spectrometry studies (FAB, MALDI and ESI-MS) an...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Tetrahedron 2004-05, Vol.60 (22), p.4789-4799
Hauptverfasser: Balog, Mirela, Grosu, Ion, Plé, Gérard, Ramondenc, Yvan, Toupet, Loı̈c, Condamine, Eric, Lange, Catherine, Loutelier-Bourhis, Corinne, Peulon-Agasse, Valérie, Bogdan, Elena
Format: Artikel
Sprache:eng
Schlagworte:
Analytical chemistry
Chemical Sciences
Ditopic ligand
ESI-MS
Macrocycle
Material chemistry
Organic chemistry
Spiro-1,3-dioxane
X-ray diffractomatry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The template synthesis of a new series of macrocycles (from monomers to tetramers) with 2,4.8,10-tetraoxaspiro[5.5]undecane units is reported. The structural analysis of the compounds is carried out using the data of high field NMR investigations, mass spectrometry studies (FAB, MALDI and ESI-MS) and the solid state X-ray diffractometry molecular structures for three compounds. Graphic
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2004.04.002