Robust Supramolecular Network on Ag(111): Hydrogen‐Bond Enhancement through Partial Alcohol Dehydrogenation

Alcohol oxidation and self‐assembly: the in situ oxidation of hydroxyl functional groups to quinone groups promotes the formation of enhanced hydrogen bonds and allows reorganization of the resulting supramolecular self‐assemblies, which evolve from a weakly bound dense phase to a strongly bound nan...

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Veröffentlicht in:Chemphyschem 2009-05, Vol.10 (7), p.1032-1035
Hauptverfasser: Pawlak, Remy, Clair, Sylvain, Oison, Vincent, Abel, Mathieu, Ourdjini, Oualid, Zwaneveld, Nikolas A. A., Gigmes, Didier, Bertin, Denis, Nony, Laurent, Porte, Louis
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Sprache:eng
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Zusammenfassung:Alcohol oxidation and self‐assembly: the in situ oxidation of hydroxyl functional groups to quinone groups promotes the formation of enhanced hydrogen bonds and allows reorganization of the resulting supramolecular self‐assemblies, which evolve from a weakly bound dense phase to a strongly bound nanoporous open structure (see picture). Alcohol oxidation and self‐assembly: the in situ oxidation of hydroxyl functional groups to quinone groups promotes the formation of enhanced hydrogen bonds and allows reorganization of the resulting supramolecular self‐assemblies, which evolve from a weakly bound dense phase to a strongly bound nanoporous open structure (see picture).
ISSN:1439-4235
1439-7641
DOI:10.1002/cphc.200900055