Polymerization of Ethylene through Reversible Addition-Fragmentation Chain Transfer (RAFT)

Polymerization of Ethylene through Reversible Addition-Fragmentation Chain Transfer (RAFT)

The present paper reports the first example of a controlled radical polymerization of ethylene using reversible addition–fragmentation chain transfer (RAFT) in the presence of xanthates (Alkyl‐OC(S)S‐R) as controlling agents under relative mild conditions (70 °C,

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2014-06, Vol.53 (26), p.6683-6686
Hauptverfasser: Dommanget, Cédric, D'Agosto, Franck, Monteil, Vincent
Format: Artikel
Sprache:eng
Schlagworte:
Addition polymerization
Chain transfer
Chemical Sciences
copolymers
Ethylene
Fragmentation
polyethylene
Polymerization
Radicals
RAFT
Rafts
Reagents
Vinyl acetate
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The present paper reports the first example of a controlled radical polymerization of ethylene using reversible addition–fragmentation chain transfer (RAFT) in the presence of xanthates (Alkyl‐OC(S)S‐R) as controlling agents under relative mild conditions (70 °C,
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201403491