Direct accessibility of mixed-metal (III/II) acid sites through the rational synthesis of porous metal carboxylates

Direct accessibility of mixed-metal (III/II) acid sites through the rational synthesis of porous metal carboxylates

The scalable and environmentally-friendly synthesis of mixed Fe(III)/M(II) (M = Ni, Co, Mg) polycarboxylate porous MOFs based on the Secondary Building Unit approach is reported. A combination of in situ infrared spectroscopy, (57)Fe Mössbauer spectrometry and adsorption microcalorimetry confirms th...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (50), p.10194-10197
Hauptverfasser: Wongsakulphasatch, S, Nouar, F, Rodriguez, J, Scott, L, Le Guillouzer, C, Devic, T, Horcajada, P, Grenèche, J-M, Llewellyn, P L, Vimont, A, Clet, G, Daturi, M, Serre, C
Format: Artikel
Sprache:eng
Schlagworte:
Accessibility
Activation
Chemical Sciences
Construction
Mossbauer effect
Nickel
Spectrometry
Spectroscopy
Synthesis
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Beschreibung
Zusammenfassung:The scalable and environmentally-friendly synthesis of mixed Fe(III)/M(II) (M = Ni, Co, Mg) polycarboxylate porous MOFs based on the Secondary Building Unit approach is reported. A combination of in situ infrared spectroscopy, (57)Fe Mössbauer spectrometry and adsorption microcalorimetry confirms the direct accessibility of the iron(III) and metal(II) sites under low temperature activation conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc02550h