Ammoxidation of allyl alcohol – a sustainable route to acrylonitrile

The ammoxidation of allyl alcohol was demonstrated over antimony-iron oxide catalysts with a Sb/Fe ratio of 0.6 and 1. Both catalysts showed high performance with 83 and 84% yield of acrylonitrile, respectively, whereby the main difference was found in the initial performance. This was ascribed to t...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2013-01, Vol.15 (11), p.3015-3019
Hauptverfasser: Guillon, Cyrille, Liebig, Carsten, Paul, Sebastien, Mamede, Anne-Sophie, Holderich, Wolfgang F, Dumeignil, Franck, Katryniok, Benjamin
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Sprache:eng
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Zusammenfassung:The ammoxidation of allyl alcohol was demonstrated over antimony-iron oxide catalysts with a Sb/Fe ratio of 0.6 and 1. Both catalysts showed high performance with 83 and 84% yield of acrylonitrile, respectively, whereby the main difference was found in the initial performance. This was ascribed to the in-operandoformation of the SbFeO sub(4) mixed oxide on the catalyst surface under reaction conditions, as proven by XPS analysis.
ISSN:1463-9262
1463-9270
DOI:10.1039/c3gc41089g