Phase transformations in the Zn–Cd–Sb system

Phase transformations in the Zn–Cd–Sb system

Phase equilibria of the Cd-Sb-Zn system have been investigated by metallographic examinations, DSC, XRD and WDS measurements. At 250DGC, the ternary diagram shows two three-phase fields, (Zn) + (Cd) + Zn4Sb3 and (Cd)+ Zn4Sb3 + (Zn,Cd)Sb. Continuous solid solution has been found between ZnSb and CdSb...

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Veröffentlicht in:Intermetallics 2003-11, Vol.11 (11-12), p.1189-1194
Hauptverfasser: Record, M.C., Izard, V., Bulanova, M., Tedenac, J.C.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Material chemistry
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Zusammenfassung:Phase equilibria of the Cd-Sb-Zn system have been investigated by metallographic examinations, DSC, XRD and WDS measurements. At 250DGC, the ternary diagram shows two three-phase fields, (Zn) + (Cd) + Zn4Sb3 and (Cd)+ Zn4Sb3 + (Zn,Cd)Sb. Continuous solid solution has been found between ZnSb and CdSb. Solubility of Cd in Sb3Zn4 was determined to be about 43 at.%. A variant of the reaction scheme is proposed for the Cd-Sb-Zn system to understand phase relations observed at 250DGC.
ISSN:0966-9795
DOI:10.1016/S0966-9795(03)00157-2