Electrochemical carboxylation of titanium to generate versatile new interfaces

Electrochemical carboxylation of titanium to generate versatile new interfaces

Titanium covered with a thin layer of titanium dioxide was reduced in aprotic polar solvents (dimethylformamide or acetonitrile) saturated with carbon dioxide in the presence of tetraalkylammonium salts (TAAX). When using tetramethylammonium salts CO2 is irreversibly reduced at potentials 

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Bibliographische Detailangaben
Veröffentlicht in:Electrochemistry communications 2018-03, Vol.88, p.67-70
1. Verfasser: Simonet, Jacques
Format: Artikel
Sprache:eng
Schlagworte:
Carbon dioxide as reagent
Carboxylated titanium
Chemical Sciences
Modified electrodes
Reduction of CO2
Titanium corrosion
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Zusammenfassung:Titanium covered with a thin layer of titanium dioxide was reduced in aprotic polar solvents (dimethylformamide or acetonitrile) saturated with carbon dioxide in the presence of tetraalkylammonium salts (TAAX). When using tetramethylammonium salts CO2 is irreversibly reduced at potentials 
ISSN:1388-2481
1873-1902
DOI:10.1016/j.elecom.2018.01.007