Asymmetric hydrogenation of 2,3-dihydro-1H-inden-1-one oxime and derivatives

Asymmetric hydrogenation of 2,3-dihydro-1H-inden-1-one oxime and derivatives

[Display omitted] Asymmetric hydrogenation of 2,3-dihydro-1H-inden-1-one oxime and derivatives to produce the corresponding optically active amine has been performed in the presence of rhodium and iridium catalysts. The optimization of neutral rhodium based catalytic systems by varying the operating...

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Veröffentlicht in:Tetrahedron: asymmetry 2016-04, Vol.27 (6), p.268-273
Hauptverfasser: Maj, Anna M., Suisse, Isabelle, Agbossou-Niedercorn, Francine
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container_end_page 273
container_issue 6
container_start_page 268
container_title Tetrahedron: asymmetry
container_volume 27
creator Maj, Anna M.
Suisse, Isabelle
Agbossou-Niedercorn, Francine
description [Display omitted] Asymmetric hydrogenation of 2,3-dihydro-1H-inden-1-one oxime and derivatives to produce the corresponding optically active amine has been performed in the presence of rhodium and iridium catalysts. The optimization of neutral rhodium based catalytic systems by varying the operating conditions and the ligand around the metallic centre led to high conversions with moderate enantiomeric excesses.
doi_str_mv 10.1016/j.tetasy.2016.02.005
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title Asymmetric hydrogenation of 2,3-dihydro-1H-inden-1-one oxime and derivatives
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