A cyclodextrin dimer as a supramolecular reaction platform for aqueous organometallic catalysis

A reaction platform based on a cyclodextrin dimer, which is able to simultaneously include a substrate in one cavity and an organometallic catalyst into the other, proved to be highly efficient for aqueous hydroformylation reaction of higher olefins.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (62), p.6989-6991
Hauptverfasser:	Blaszkiewicz, Claire, Bricout, Hervé, Léonard, Estelle, Len, Christophe, Landy, David, Cézard, Christine, Djedaïni-Pilard, Florence, Monflier, Eric, Tilloy, Sébastien
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes - chemical synthesis Aldehydes - chemistry Alkenes - chemistry Catalysis Catalysts Chemical Sciences Cyclodextrins Cyclodextrins - chemistry Dimerization Dimers Holes Macromolecular Substances - chemistry Metalorganic compounds Molecular Dynamics Simulation Molecular Structure Olefins Organometallic Compounds - chemistry Platforms Water - chemistry
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Beschreibung
Zusammenfassung:	A reaction platform based on a cyclodextrin dimer, which is able to simultaneously include a substrate in one cavity and an organometallic catalyst into the other, proved to be highly efficient for aqueous hydroformylation reaction of higher olefins.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c3cc43647k