Ratiometric mixed Eu-Tb metal-organic framework as a new cryogenic luminescent thermometer

We report a new mixed Eu-Tb metal-organic framework shown to be a highly effective dual-emitting luminescent thermometer within the cryogenic range and showing a relative thermal sensitivity of 3.26% K −1 at 35.5 K. The first example of a dual-emitting luminescent thermometer based on lanthanide iso...

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Veröffentlicht in:Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2017, Vol.5 (42), p.1933-1937
Hauptverfasser: N'Dala-Louika, Isis, Ananias, Duarte, Latouche, Camille, Dessapt, Rémi, Carlos, Luís D, Serier-Brault, Hélène
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Sprache:eng
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Zusammenfassung:We report a new mixed Eu-Tb metal-organic framework shown to be a highly effective dual-emitting luminescent thermometer within the cryogenic range and showing a relative thermal sensitivity of 3.26% K −1 at 35.5 K. The first example of a dual-emitting luminescent thermometer based on lanthanide isophthalate exhibiting a maximum relative sensitivity of 3.26% K −1 , a temperature uncertainty of 0.07 K at 35.5 K, and a repeatability >99.9% between 12 and 230 K.
ISSN:2050-7526
2050-7534
DOI:10.1039/c7tc03223d