m-phosphonobenzoic acid and copper(II) as precursors of helical chain and lamellar hybrid materials

m-phosphonobenzoic acid and copper(II) as precursors of helical chain and lamellar hybrid materials

A 1D helical-chain material Cu6(H2O)7(m-PO3C6H4CO2)41, characterized by a non-centrosymmetric crystal structure, and a 2D lamellar hybrid material Cu(H2O)(m-PO3C6H4CO2H) 2 have been synthesised starting from m-phosphonobenzoic acid and copper(II). The pH of the reaction media regulates the formation...

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Veröffentlicht in:CrystEngComm 2009-01, Vol.11 (4), p.556
Hauptverfasser: Rueff, Jean-Michel, Caignaert, Vincent, Leclaire, André, Simon, Charles, Haelters, Jean-Pierre, Jaffrès, Paul-Alain
Format: Artikel
Sprache:eng
Schlagworte:
Analytical chemistry
Chemical Sciences
Coordination chemistry
Cristallography
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Zusammenfassung:A 1D helical-chain material Cu6(H2O)7(m-PO3C6H4CO2)41, characterized by a non-centrosymmetric crystal structure, and a 2D lamellar hybrid material Cu(H2O)(m-PO3C6H4CO2H) 2 have been synthesised starting from m-phosphonobenzoic acid and copper(II). The pH of the reaction media regulates the formation of either 1 or 2.
ISSN:1466-8033
1466-8033
DOI:10.1039/b816132c