Room-Temperature Characterization of a Mixed-Valent μ‑Hydroxodicopper(II,III) Complex

Room-Temperature Characterization of a Mixed-Valent μ‑Hydroxodicopper(II,III) Complex

Bis­(μ-hydroxo)­dicopper­(II,II) bearing a naphthyridine-based ligand has been synthesized and characterized in the solid state and solution. Cyclic voltammetry at room temperature displays a reversible redox system that corresponds to the monoelectronic oxidation of the complex. Spectroscopic and t...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry 2016-09, Vol.55 (17), p.8263-8266
Hauptverfasser: Isaac, James A, Gennarini, Federica, López, Isidoro, Thibon-Pourret, Aurore, David, Rolf, Gellon, Gisèle, Gennaro, Béatrice, Philouze, Christian, Meyer, Franc, Demeshko, Serhiy, Le Mest, Yves, Réglier, Marius, Jamet, Hélène, Le Poul, Nicolas, Belle, Catherine
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Coordination chemistry
Inorganic chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Bis­(μ-hydroxo)­dicopper­(II,II) bearing a naphthyridine-based ligand has been synthesized and characterized in the solid state and solution. Cyclic voltammetry at room temperature displays a reversible redox system that corresponds to the monoelectronic oxidation of the complex. Spectroscopic and time-resolved spectroelectrochemical data coupled to theoretical results support the formation of a charge-localized mixed-valent CuII,III 2 species.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.6b01504