N-N bond formation in Ugi processes: from nitric acid to libraries of nitramines

N-N bond formation in Ugi processes: from nitric acid to libraries of nitramines

The Ugi reaction has drawn considerable attention over the years leading to numerous libraries of heterocycles and various extensions changing the nature of the components of the coupling. We report here the use of nitric acid as carboxylic acids surrogates, displaying the first aminative Ugi-type r...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (13), p.2118-2121
Hauptverfasser: Mercalli, Valentina, Nyadanu, Aude, Cordier, Marie, Tron, Gian Cesare, Grimaud, Laurence, El Kaim, Laurent
Format: Artikel
Sprache:eng
Schlagworte:
Bonding
Carboxylic acids
Chemical Sciences
Coupling
Libraries
Nitric acid
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Zusammenfassung:The Ugi reaction has drawn considerable attention over the years leading to numerous libraries of heterocycles and various extensions changing the nature of the components of the coupling. We report here the use of nitric acid as carboxylic acids surrogates, displaying the first aminative Ugi-type reaction leading to nitramines.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc10288c