Enantioselective Synthesis of Carbocycles and Heterocycles by Radical/Polar and Polar/Radical Cascades

Radically efficient: New and appealing enantioselective cyclizations leading to highly functionalized carbocycles and heterocycles have been reported (see scheme; TMS=trimethylsilyl). These methodologies, based on the cascade combination of radical and polar steps, provide alternatives to convention...

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Veröffentlicht in:	Angewandte Chemie International Edition 2013-01, Vol.52 (3), p.809-811
Hauptverfasser:	Mondal, Shovan, Bertrand, Michèle P., Nechab, Malek
Format:	Artikel
Sprache:	eng
Schlagworte:	asymmetric synthesis carbocycles Cascades Chemical Sciences cyclization heterocycles Radicals Synthesis
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creator	Mondal, Shovan Bertrand, Michèle P. Nechab, Malek
description	Radically efficient: New and appealing enantioselective cyclizations leading to highly functionalized carbocycles and heterocycles have been reported (see scheme; TMS=trimethylsilyl). These methodologies, based on the cascade combination of radical and polar steps, provide alternatives to conventional methodologies.
doi_str_mv	10.1002/anie.201207518
format	Article
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Chem. Int. Ed</addtitle><description>Radically efficient: New and appealing enantioselective cyclizations leading to highly functionalized carbocycles and heterocycles have been reported (see scheme; TMS=trimethylsilyl). 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subjects	asymmetric synthesis carbocycles Cascades Chemical Sciences cyclization heterocycles Radicals Synthesis
title	Enantioselective Synthesis of Carbocycles and Heterocycles by Radical/Polar and Polar/Radical Cascades
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