Dehydrogenative Allylic Aminations of But-3-enoic Acid Derivatives

Dehydrogenative Allylic Aminations of But-3-enoic Acid Derivatives

Abstract Two complementary Pd-catalyzed protocols enabling the γ-selective intermolecular allylic amination of but-3-enoic acid derivatives are reported. These transformations can be successfully achieved via either­ a direct Pd(II)-catalyzed protocol or by way of a one-pot Pd(II)/Pd(0)-catalyzed se...

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Veröffentlicht in:Synthesis (Stuttgart) 2016-10, Vol.48 (19), p.3400-3412
Hauptverfasser: Diamante, Daria, Gabrieli, Sara, Benincori, Tiziana, Broggini, Gianluigi, Oble, Julie, Poli, Giovanni
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container_end_page 3412
container_issue 19
container_start_page 3400
container_title Synthesis (Stuttgart)
container_volume 48
creator Diamante, Daria
Gabrieli, Sara
Benincori, Tiziana
Broggini, Gianluigi
Oble, Julie
Poli, Giovanni
description Abstract Two complementary Pd-catalyzed protocols enabling the γ-selective intermolecular allylic amination of but-3-enoic acid derivatives are reported. These transformations can be successfully achieved via either­ a direct Pd(II)-catalyzed protocol or by way of a one-pot Pd(II)/Pd(0)-catalyzed sequence, depending on the nature of the nitrogen nucleophile used.
doi_str_mv 10.1055/s-0035-1562453
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title Dehydrogenative Allylic Aminations of But-3-enoic Acid Derivatives
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