A propeller-shaped μ4-carbonate hexanuclear dysprosium complex with a high energetic barrier to magnetisation relaxation

A propeller-shaped μ4-carbonate hexanuclear dysprosium complex with a high energetic barrier to magnetisation relaxation

A Dy6 complex composed of two Dy3 triangular units, [Dy6(μ3-OH)(CO3)3(bsc)3(MeOH)14(H2O)](Cl)5·(H2O)·(MeOH)2 (1), was isolated and found to exhibit slow relaxation of the magnetisation under zero applied dc field, resulting in a high energetic barrier to relaxation.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2016, Vol.45 (42), p.16769-16773
Hauptverfasser: Holmberg, Rebecca J, Kuo, Che-Jung, Gabidullin, Bulat, Wang, Chia-Wei, Clérac, Rodolphe, Murugesu, Muralee, Lin, Po-Heng
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Material chemistry
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container_end_page 16773
container_issue 42
container_start_page 16769
container_title Dalton transactions : an international journal of inorganic chemistry
container_volume 45
creator Holmberg, Rebecca J
Kuo, Che-Jung
Gabidullin, Bulat
Wang, Chia-Wei
Clérac, Rodolphe
Murugesu, Muralee
Lin, Po-Heng
description A Dy6 complex composed of two Dy3 triangular units, [Dy6(μ3-OH)(CO3)3(bsc)3(MeOH)14(H2O)](Cl)5·(H2O)·(MeOH)2 (1), was isolated and found to exhibit slow relaxation of the magnetisation under zero applied dc field, resulting in a high energetic barrier to relaxation.
doi_str_mv 10.1039/c6dt02873j
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subjects Chemical Sciences
Material chemistry
title A propeller-shaped μ4-carbonate hexanuclear dysprosium complex with a high energetic barrier to magnetisation relaxation
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