A propeller-shaped μ4-carbonate hexanuclear dysprosium complex with a high energetic barrier to magnetisation relaxation

A propeller-shaped μ4-carbonate hexanuclear dysprosium complex with a high energetic barrier to magnetisation relaxation

A Dy6 complex composed of two Dy3 triangular units, [Dy6(μ3-OH)(CO3)3(bsc)3(MeOH)14(H2O)](Cl)5·(H2O)·(MeOH)2 (1), was isolated and found to exhibit slow relaxation of the magnetisation under zero applied dc field, resulting in a high energetic barrier to relaxation.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2016, Vol.45 (42), p.16769-16773
Hauptverfasser: Holmberg, Rebecca J, Kuo, Che-Jung, Gabidullin, Bulat, Wang, Chia-Wei, Clérac, Rodolphe, Murugesu, Muralee, Lin, Po-Heng
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Material chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A Dy6 complex composed of two Dy3 triangular units, [Dy6(μ3-OH)(CO3)3(bsc)3(MeOH)14(H2O)](Cl)5·(H2O)·(MeOH)2 (1), was isolated and found to exhibit slow relaxation of the magnetisation under zero applied dc field, resulting in a high energetic barrier to relaxation.
ISSN:1477-9226
1477-9234
DOI:10.1039/c6dt02873j