Reaction of a chiral oxygen–sulfur paired bidentate ligand with nickel and iron boride: asymmetric borane reduction of ketones
An α-thio alcohol derived from camphor is anchored to nickel boride provided the nickel surface atoms have been passivated. The resulting heterogeneous catalyst affords moderate enantioselectivity in the reduction of acetophenone. Graphic
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| Veröffentlicht in: | Tetrahedron: asymmetry 2001-08, Vol.12 (14), p.1971-1973 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | An α-thio alcohol derived from camphor is anchored to nickel boride provided the nickel surface atoms have been passivated. The resulting heterogeneous catalyst affords moderate enantioselectivity in the reduction of acetophenone.
Graphic |
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| ISSN: | 0957-4166 1362-511X 0957-4166 |
| DOI: | 10.1016/S0957-4166(01)00357-3 |