Crystalline-like structures and multilayering in Langmuir films of ionic liquids at the air-water interface

Crystalline-like structures and multilayering in Langmuir films of ionic liquids at the air-water interface

Langmuir films of [C18mim][NTf2] ionic liquid exhibited, for the first time, the reversible formation of crystalline-like structures at the surface of water, compatible with the formation of multilayers. Atomistic molecular dynamics simulation results support the experimental findings, unambiguously...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-04, Vol.52 (32), p.5585-5588
Hauptverfasser: Filipe, Eduardo J M, Morgado, Pedro, Teixeira, Miguel, Shimizu, Karina, Bonatout, Nathalie, Goldmann, Michel, Canongia Lopes, José Nuno
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Crystal structure
Formations
Ionic liquids
Langmuir-Blodgett films
Molecular dynamics
Molecular structure
Multilayers
Simulation
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Beschreibung
Zusammenfassung:Langmuir films of [C18mim][NTf2] ionic liquid exhibited, for the first time, the reversible formation of crystalline-like structures at the surface of water, compatible with the formation of multilayers. Atomistic molecular dynamics simulation results support the experimental findings, unambiguously indicating the existence of a trilayer.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc01368f