Revisiting the Metathesis of 13C-Monolabeled Ethane

The metathesis of 13C-monolabeled ethane leads to the parallel occurrence of degenerate and productive reactions, affording the statistical distribution of the various product isotopomers, which can be rationalized in terms of a mechanistic reaction scheme combining both processes.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organometallics 2010-12, Vol.29 (23), p.6612-6614
Hauptverfasser: Maury, Olivier, Lefort, Laurent, Vidal, Véronique, Thivolle-Cazat, Jean, Basset, Jean-Marie
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The metathesis of 13C-monolabeled ethane leads to the parallel occurrence of degenerate and productive reactions, affording the statistical distribution of the various product isotopomers, which can be rationalized in terms of a mechanistic reaction scheme combining both processes.
ISSN:0276-7333
1520-6041
DOI:10.1021/om100542k