Transesterification of vegetable oils by AlPOxNy heterogeneous catalysts

[Display omitted] •High specific surface areas AlPO4 precursors prepared by hydrogel or citrate routes.•Reactive AlPOxNy catalysts are prepared and characterized.•Nitridophosphates catalyze the transesterification reaction of vegetable oils.•Higher catalytic performances compared to the reference catalyst ZnAl2O4. AlPOxNy are the most studied materials among nitrided phosphates in heterogeneous catalysis. Such catalysts were tested in this work for the transesterification reaction of canola oil. High specific surface areas AlPO4 precursors have been prepared using hydrogel or citrate routes. Nitrided powders obtained after thermal reaction under ammonia flow keep high surface areas and nitrogen contents can be modulated depending on the experimental conditions. Both precursor and oxynitrides have been characterized by BET, oxygen and nitrogen analyses, infrared and NMR spectroscopies. The influence of the metal, the alcohol and the nitrogen content on the catalytic performances was also studied. AlPO4 and corresponding nitrided phases (with N wt.%