Hydrogen Storage in Semiclathrate Hydrates of Tetrabutyl Ammonium Chloride and Tetrabutyl Phosphonium Bromide

Original calorimetric and phase equilibrium properties for hydrogen + tetrabutylammonium bromide (TBAB), tetrabutylammonium chloride (TBACl), or tetrabutylphosphonium bromide (TBPB) semiclathrate hydrates were measured using differential scanning calorimetry under pressure. The dissociation temperat...

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Veröffentlicht in:Journal of chemical and engineering data 2010-09, Vol.55 (9), p.3395-3399
Hauptverfasser: Deschamps, Johnny, Dalmazzone, Didier
Format: Artikel
Sprache:eng
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Zusammenfassung:Original calorimetric and phase equilibrium properties for hydrogen + tetrabutylammonium bromide (TBAB), tetrabutylammonium chloride (TBACl), or tetrabutylphosphonium bromide (TBPB) semiclathrate hydrates were measured using differential scanning calorimetry under pressure. The dissociation temperatures of H2 + TBACl and H2 + TBPB semiclathrate hydrates are very close to the ambient temperature at low pressures around 15.0 MPa. H2 + TBACl and H2 + TBPB systems therefore exhibit better and comparable stability than the H2 + TBAB system at equivalent pressure, respectively. The amount of hydrogen stored in H2 + TBACl and H2 + TBPB semiclathrate hydrates was estimated in terms of the H2-to-water mole ratio (n H2 /n H2O) calculated from disssociation enthalpies and (p, T) equilibrium data. In terms of mass fraction deduced from the ratio (n H2 /n H2O), H2 + TBACl and H2 + TBPB semiclathrate hydrates can store 0.12 % and 0.14 % of hydrogen, respectively. Moreover, the quantity of hydrogen stored in these two semiclathrate hydrates is significantly higher than that stored in the H2 + TBAB system.
ISSN:0021-9568
1520-5134
DOI:10.1021/je100146b