Iron-catalyzed selective reduction of nitro compounds to amines

Iron-catalyzed selective reduction of nitro compounds to amines

An efficient reduction of the nitro group with a catalytic amount of Fe(acac) 3 and TMDS in THF at 60 °C affording the corresponding amine is described.

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Bibliographische Detailangaben
Veröffentlicht in:Tetrahedron letters 2010-04, Vol.51 (15), p.1939-1941
Hauptverfasser: Pehlivan, Leyla, Métay, Estelle, Laval, Stéphane, Dayoub, Wissam, Demonchaux, Patrice, Mignani, Gérard, Lemaire, Marc
Format: Artikel
Sprache:eng
Schlagworte:
1,1,3,3-Tetramethyldisiloxane
Amines
Chemical Sciences
Iron catalyst
Nitro
Organic chemistry
Reduction
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Beschreibung
Zusammenfassung:An efficient reduction of the nitro group with a catalytic amount of Fe(acac) 3 and TMDS in THF at 60 °C affording the corresponding amine is described.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2010.01.067