Barium-Mediated Cross-Dehydrocoupling of Hydrosilanes with Amines
Alkaline-earth (most prominently barium) complexes of the type [Ae{N(SiMe3 )2 }2 ⋅(THF)x ] and [{N^N}Ae{N(SiMe3 )2 }⋅(THF)x ] are very active and productive precatalysts (TON=396, TOF up to 3600 h(-1) ; Ca
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| Veröffentlicht in: | Angewandte Chemie International Edition 2015-06, Vol.54 (26), p.7679-7683 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
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| Online-Zugang: | Volltext |
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| Zusammenfassung: | Alkaline-earth (most prominently barium) complexes of the type [Ae{N(SiMe3 )2 }2 ⋅(THF)x ] and [{N^N}Ae{N(SiMe3 )2 }⋅(THF)x ] are very active and productive precatalysts (TON=396, TOF up to 3600 h(-1) ; Ca |
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| ISSN: | 1433-7851 1521-3773 |
| DOI: | 10.1002/anie.201502956 |