A New Class of C3-Symmetrical Hemicryptophane Hosts: Triamide- and Tren-hemicryptophanes

The first hemicryptophanes derived from tris(N-alkyl-carbamoylmethyl)amine and tris(2-aminoethyl)amine (tren) have been synthesized following a single synthetic pathway that allows the subsequent formation of the two heteroditopic hosts 3 and 4. X-ray crystal structures show a well-defined cavity en...

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Veröffentlicht in:	Journal of organic chemistry 2010-03, Vol.75 (6), p.2099-2102
Hauptverfasser:	RAYTCHEV, Pascal Dimitrov, PERRAUD, Olivier, ARONICA, Christophe, MARTINEZ, Alexandre, DUTASTA, Jean-Pierre
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Chemistry Coordination compounds Crystallography, X-Ray Ethylenediamines - chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms Inorganic chemistry and origins of life Magnetic Resonance Spectroscopy Models, Molecular Molecular Structure or physical chemistry Organic chemistry Polycyclic Compounds Preparations and properties Theoretical and Triazoles - chemistry
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Beschreibung
Zusammenfassung:	The first hemicryptophanes derived from tris(N-alkyl-carbamoylmethyl)amine and tris(2-aminoethyl)amine (tren) have been synthesized following a single synthetic pathway that allows the subsequent formation of the two heteroditopic hosts 3 and 4. X-ray crystal structures show a well-defined cavity encapsulating a solvent guest for both compounds emphasizing their complexation properties.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo100052r