'Auto-click' functionalization for diversified copper(I) and gold(I) NHCs

Azide-tagged Cu(I)-NHC reacts in an 'auto-click' process to furnish complexes functionalized by 1,2,3-triazoles bearing diverse substituents. The resulting Cu(I) complexes are amenable to further transmetallation to Au(I). The whole strategy proceeds with mild conditions and constitutes an...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2014-05, Vol.43 (19), p.6981-6989
Hauptverfasser:	Ibrahim, Houssein, Gibard, Clémentine, Hesling, Cédric, Guillot, Régis, Morel, Laurent, Gautier, Arnaud, Cisnetti, Federico
Format:	Artikel
Sprache:	eng
Schlagworte:	Bearing Cell Line, Tumor Chemical Sciences Click Chemistry Coordination Complexes - chemical synthesis Coordination Complexes - chemistry Coordination Complexes - metabolism Copper - chemistry Crystallography, X-Ray Gold - chemistry Heterocyclic Compounds - chemistry Humans Microscopy, Confocal Molecular Conformation Strategy Triazoles - chemistry
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Beschreibung
Zusammenfassung:	Azide-tagged Cu(I)-NHC reacts in an 'auto-click' process to furnish complexes functionalized by 1,2,3-triazoles bearing diverse substituents. The resulting Cu(I) complexes are amenable to further transmetallation to Au(I). The whole strategy proceeds with mild conditions and constitutes an efficient entry to functionalised metal-NHCs with biorelevant moieties.
ISSN:	1477-9226 1477-9234
DOI:	10.1039/c4dt00429a