Aromatic Nucleophilic Substitution (SNAr) of meso-Nitroporphyrin with Azide and Amines as an Alternative Metal Catalyst Free Synthetic Approach To Obtain meso-N‑Substituted Porphyrins

Aromatic Nucleophilic Substitution (SNAr) of meso-Nitroporphyrin with Azide and Amines as an Alternative Metal Catalyst Free Synthetic Approach To Obtain meso-N‑Substituted Porphyrins

Aromatic nucleophilic substitution reaction of the nitro group of meso-nitroporphyrins with azide and various amines was achieved and represents an alternative procedure to C–N coupling reactions usually needed to obtain such meso-N-substituted porphyrins in good yields.

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Veröffentlicht in:Journal of organic chemistry 2014-07, Vol.79 (14), p.6424-6434
Hauptverfasser: Devillers, Charles H, Hebié, Seydou, Lucas, Dominique, Cattey, Hélène, Clément, Sébastien, Richeter, Sébastien
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Organic chemistry
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Zusammenfassung:Aromatic nucleophilic substitution reaction of the nitro group of meso-nitroporphyrins with azide and various amines was achieved and represents an alternative procedure to C–N coupling reactions usually needed to obtain such meso-N-substituted porphyrins in good yields.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo5005586