Effect of varying conditions of exposure to an aggressive medium on the corrosion behavior of the 2050 Al–Cu–Li alloy

•After natural ageing, intergranular corrosion was observed for the 2050 alloy.•After artificial ageing at 155°C, transgranular corrosion was observed.•The corrosion behavior of alloy 2050 depended on the distribution of T1 precipitates.•Cyclic corrosion tests induced subgrain boundary dissolution.•...

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Veröffentlicht in:Corrosion science 2014-08, Vol.85, p.455-470
Hauptverfasser: Guérin, Mathilde, Andrieu, Eric, Odemer, Grégory, Alexis, Joël, Blanc, Christine
Format: Artikel
Sprache:eng
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Zusammenfassung:•After natural ageing, intergranular corrosion was observed for the 2050 alloy.•After artificial ageing at 155°C, transgranular corrosion was observed.•The corrosion behavior of alloy 2050 depended on the distribution of T1 precipitates.•Cyclic corrosion tests induced subgrain boundary dissolution.•Hydrogen trapping at T1 precipitates was evidenced for artificially aged 2050 alloy. The corrosion behavior of aluminum alloy 2050 was studied as a function of varying conditions of exposure to an aqueous NaCl solution. Two metallurgical states were considered, i.e., an as-received alloy (NHT) and aged samples (HT). After continuous immersion tests, the NHT samples were susceptible to intergranular corrosion, whereas intragranular corrosion was observed for the HT samples. For the NHT samples, cyclic corrosion tests, with alternate immersion – emersion periods, induced subgrain boundary dissolution, and for the HT samples, grain and/or subgrain boundary sensibilization was induced. Hydrogen content measurements suggested a hydrogen enrichment of the alloy under cyclic corrosion tests.
ISSN:0010-938X
1879-0496
DOI:10.1016/j.corsci.2014.04.042