Formylation of amines through catalyst- and solvent-free transamidation reaction
The transamidation between formamide and various amines proceeds under heating, without any catalyst nor solvent, providing thus green and neutral conditions for the formylation of primary and secondary amines. The resulting amide product can be directly transformed, in a one pot sequence, into mono...
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| Veröffentlicht in: | Tetrahedron letters 2014-01, Vol.55 (2), p.362-364 |
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| creator | Lebleu, Thomas Kotsuki, Hiyoshizo Maddaluno, Jacques Legros, Julien |
| description | The transamidation between formamide and various amines proceeds under heating, without any catalyst nor solvent, providing thus green and neutral conditions for the formylation of primary and secondary amines. The resulting amide product can be directly transformed, in a one pot sequence, into monomethylamine. |
| doi_str_mv | 10.1016/j.tetlet.2013.11.029 |
| format | Article |
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| fulltext | fulltext |
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| ispartof | Tetrahedron letters, 2014-01, Vol.55 (2), p.362-364 |
| issn | 0040-4039 1873-3581 |
| language | eng |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Amide Amides Amines Catalysts Chemical Sciences Green chemistry Heating High pressure Monomethylation Neat conditions Organic chemistry Solvents Tetrahedrons |
| title | Formylation of amines through catalyst- and solvent-free transamidation reaction |
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