Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand

Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand

Attempts to install a tridentate aniline–NHC–phenol (NCO) ligand on titanium and zirconium led instead to complexes resulting from unexpected rearrangement pathways that illustrate common behavior in carbene–early-transition-metal chemistry.

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Veröffentlicht in:Organometallics 2013-05, Vol.32 (10), p.2934-2938
Hauptverfasser: Despagnet-Ayoub, Emmanuelle, Henling, Lawrence M, Labinger, Jay A, Bercaw, John E
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Coordination chemistry
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Beschreibung
Zusammenfassung:Attempts to install a tridentate aniline–NHC–phenol (NCO) ligand on titanium and zirconium led instead to complexes resulting from unexpected rearrangement pathways that illustrate common behavior in carbene–early-transition-metal chemistry.
ISSN:0276-7333
1520-6041
DOI:10.1021/om4001567