A heterotrimetallic 3d-3d'-4f single chain magnet constructed from anisotropic high-spin 3d-4f nodes and paramagnetic spacers

A heterotrimetallic 3d-3d'-4f single chain magnet constructed from anisotropic high-spin 3d-4f nodes and paramagnetic spacers

By connecting [LCuTb](3+) nodes with [Fe(CN)₆]³⁻ spacers a 1-D coordination polymer with slow relaxation of magnetization is obtained (L²⁻ is the N,N'-propylene-bis(3-methoxysalicylideneiminato) anion).

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2010-01, Vol.39 (20), p.4734-4736
Hauptverfasser: Gheorghe, Ruxandra, Madalan, Augustin M, Costes, Jean-Pierre, Wernsdorfer, Wolfgang, Andruh, Marius
Format: Artikel
Sprache:eng
Schlagworte:
Anions
Chains (polymeric)
Construction
Coordination polymers
Joining
Magnetization
Physics
Prints
Spacers
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Beschreibung
Zusammenfassung:By connecting [LCuTb](3+) nodes with [Fe(CN)₆]³⁻ spacers a 1-D coordination polymer with slow relaxation of magnetization is obtained (L²⁻ is the N,N'-propylene-bis(3-methoxysalicylideneiminato) anion).
ISSN:1477-9226
1477-9234
DOI:10.1039/b925636a