Radicals from aldehydes: A convergent access to dienes and d-lactones
A convenient method for the generation of O,S-acetal xanthates from aldehydes has been developed. The corresponding nucleophilic radicals undergo facile addition to unactivated olefins and the resulting adducts can be further elaborated to generate dienes and unsaturated d-lactones. © Georg Thieme V...
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| Veröffentlicht in: | Synlett 2006 (10), p.1485-1490 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A convenient method for the generation of O,S-acetal xanthates from aldehydes has been developed. The corresponding nucleophilic radicals undergo facile addition to unactivated olefins and the resulting adducts can be further elaborated to generate dienes and unsaturated d-lactones. © Georg Thieme Verlag Stuttgart. |
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| ISSN: | 0936-5214 1437-2096 |
| DOI: | 10.1055/s-2006-941582 |