Methylcyanobutadiyne: Synthesis, X-ray Structure and Photochemistry; Towards an Explanation of Its Formation in the Interstellar Medium

Methylcyanobutadiyne: Synthesis, X-ray Structure and Photochemistry; Towards an Explanation of Its Formation in the Interstellar Medium

Out of this world: A new convenient synthesis of methylcyanobutadiyne (see figure), an interstellar compound, is described. It was characterized by various techniques including X‐ray structure determination. Photolysis experiments were carried out on binary gaseous mixtures of interstellar relevant...

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Veröffentlicht in:Chemistry : a European journal 2013-12, Vol.19 (52), p.17683-17686
Hauptverfasser: Kerisit, Nicolas, Toupet, Loïc, Trolez, Yann, Guillemin, Jean-Claude
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Chemistry
cyanopolyynes
Formations
Inorganic chemistry
Interstellar
interstellar chemistry
Interstellar matter
methylcyanobutadiyne
Photochemistry
Photolysis
Synthesis
synthetic methods
X-rays
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Zusammenfassung:Out of this world: A new convenient synthesis of methylcyanobutadiyne (see figure), an interstellar compound, is described. It was characterized by various techniques including X‐ray structure determination. Photolysis experiments were carried out on binary gaseous mixtures of interstellar relevant compounds to understand how methylcyanobutadiyne could be formed in the interstellar medium.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201303377